Sign up with Skype, one of the most well-known VoIP providers, as of 2010. It allows free PC-to-PC voice and video calls. Start the application, right-click on one of your chat buddies and select "Call" to begin a voice chat.
Download Google Talk. This service uses your Google account to connect you with your friends via VoIP calls or text chats. Open up a new chat with one of your friends and click the "Call" button at the top to begin a free VoIP call.
Install ooVoo, one of the best VoIP and video chat clients available, as of 2010. In addition to providing free PC-to-PC VoIP calls, it allows you to have up to six people participate in a video call. To start a voice chat with a friend, right-click on her name in your friends list and choose "Call."
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